To give you a little background, I work for a school district with over 27k clients managed through SCCM. Those of you who have already fought with the application know that VLC is a user-based installation. The following assumes you have a healthy SCCM 2012 environment setup and are attempting to install VLC 2.2.2 (64-bit).
I'll give you the gist, it just won't be as pretty.
I wrote a well manicured post that gave a play-by-play walkthrough of VLC 2.2.2 deployment, but got sidetracked testing a different deployment and came back to my computer to find my post eaten due to excessive idling.